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Chemistry 12 · Chemistry · Lesson 2.5

The equilibrium constant

Level
Grade 12
Reading time
11 min reading
Review
Last reviewed 2026-09-03
Errata

Abstract

Writing and interpreting Keq.

What is the equilibrium constant (Keq)?

Short answer

The equilibrium constant, Keq, describes the ratio of products to reactants at equilibrium for a reversible reaction. It equals the product concentrations divided by the reactant concentrations, each raised to its coefficient in the balanced equation. A large Keq means products are favoured; a small Keq means reactants are favoured. Keq depends only on temperature.

Concept preview

What you will be able to do

  1. 01Write an equilibrium expression from a balanced equation
  2. 02Interpret the magnitude of Keq
  3. 03Use the reaction quotient Q to predict the direction of reaction

Every equilibrium is summarised by a single number, the equilibrium constant Keq, which captures the balance point of the reaction. You construct its expression directly from the balanced equation: put the product concentrations in the numerator and the reactant concentrations in the denominator, and raise each concentration to the power of its coefficient. For the general reaction aA+bB⇌cC+dDaA + bB \rightleftharpoons cC + dD, the expression is Keq=[C]c[D]d[A]a[B]bK_{eq} = \dfrac{[C]^c[D]^d}{[A]^a[B]^b}.

School Plan

The equilibrium constant

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Related topics

Frequently asked questions

What does a large Keq tell you?
That at equilibrium the reaction lies far toward the products — they dominate the mixture.
Does Keq change with concentration?
No. Keq changes only with temperature; adding reactants or products shifts the position of equilibrium but not the constant.