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Grade 11 · Chemistry

Empirical and molecular formulae

Why it matters

Finding the simplest ratio and then the true molecular formula.

Core20m readingPrerequisite: Percentage composition

What is the difference between empirical and molecular formula?

Short answer

An empirical formula gives the simplest whole-number ratio of atoms in a compound; a molecular formula gives the actual number of each atom in one molecule. The molecular formula is always a whole-number multiple of the empirical formula — for example, hydrogen peroxide is empirical HO but molecular H₂O₂ (twice the empirical unit).

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Frequently asked questions

How do you find the molecular formula from the empirical formula?
Divide the compound’s molar mass by the empirical formula mass to get a whole number, then multiply the empirical formula by it.