AP Chemistry · Chemistry · Lesson 5.1
Reaction Rates
- Level
- Advanced Placement (AP)
- Reading time
- 12 min reading
- Review
- Last reviewed 2026-09-03
- Standard
- Accuracy standard
- Errata
Abstract
Defining and measuring rate.
What is a rate law in chemistry?
Short answer
A rate law is an equation that relates the rate of a reaction to the concentrations of its reactants, each raised to an experimentally determined power called its order. It has the form rate = k[A]^m[B]^n, where k is the rate constant. Rate laws are found from experiment, not from the balanced equation, and reveal information about the reaction mechanism.
Concept preview
What you will be able to do
- 01Define reaction rate and identify the factors affecting it.
- 02Derive and use rate laws to determine reaction rates from experimental data.
- 03Understand the relationship between reaction mechanisms and rate laws.
- 04Interpret and analyse graphical representations of reaction rates.
The reaction rate is a fundamental concept in chemical kinetics, representing how quickly a chemical reaction proceeds. It is crucial for understanding how chemical processes occur in both natural and industrial settings. Mathematically, the rate of a reaction is defined as the change in concentration of a reactant or product per unit time. This can be expressed as for a reactant , where the negative sign indicates that the concentration of a reactant decreases over time. Conversely, for a product, the rate is expressed as , where is a product. Reaction rates are typically measured in units of molarity per second (M/s). Understanding reaction rates allows chemists to control reactions to optimize yields and minimize by-products.
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Reaction Rates
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Related topics
Frequently asked questions
- How is reaction order determined?
- Experimentally — by measuring how the rate changes when each reactant’s concentration is varied.
- Can you read the rate law from the balanced equation?
- No. Orders must be found by experiment; they are not the stoichiometric coefficients.