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Chemistry 11 · Chemistry · Lesson 3.3

Naming ionic compounds and hydrates

Level
Grade 11
Reading time
11 min reading
Review
Last reviewed 2026-09-03
Errata

Abstract

Naming from a formula (Stock system) and naming hydrates.

How do you name ionic compounds?

Short answer

To name an ionic compound, name the cation (metal) first, then the anion (non-metal) with its ending changed to -ide, as in sodium chloride. Polyatomic ions keep their own names. When a metal forms more than one charge, a Roman numeral shows which one, as in iron(III) oxide. No prefixes are used for ionic compounds.

Concept preview

What you will be able to do

  1. 01Name simple ionic compounds from their formulas
  2. 02Use the un-criss-cross method to find a metal's charge
  3. 03Name hydrated ionic compounds

Naming is the reverse of formula-writing. If the first (metal) ion has only one possible charge, simply write the names of the two ions in order, dropping the word 'ion'. So ZnCl2\mathrm{ZnCl_2} is zinc chloride (Zn2+\mathrm{Zn^{2+}} = zinc, Cl−\mathrm{Cl^-} = chloride) and Ag2SO4\mathrm{Ag_2SO_4} is silver sulfate. You can assume the negative ion has its one usual charge from the table.

School Plan

Naming ionic compounds and hydrates

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Related topics

Frequently asked questions

When do you use a Roman numeral in an ionic name?
When the metal can have more than one charge (like iron or copper), the numeral shows which charge it has in that compound.
Do ionic compounds use prefixes like "di" or "tri"?
No. Prefixes are used only for molecular compounds; ionic names are set by the ion charges.